288613-60-5Relevant academic research and scientific papers
Phosphine-substituted porphyrins as supramolecular building blocks
Darling, Scott L.,Stulz, Eugen,Feeder, Neil,Bampos, Nick,Sanders, Jeremy K. M.
, p. 261 - 264 (2007/10/03)
A route to alkyne-phosphine-substituted metalloporphyrins is presented. The X-ray structure of the methanol adduct of a diphenylphosphine Zn(II) porphyrin reveals solid state dimerisation accompanied by proton transfer from coordinated methanol to phosphine in a process reminiscent of carbonic anhydrase. The ability of the phosphine-substituted porphyrins to form non- covalent arrays with a Ru(II) porphyrin was explored using 1H/31P NMR and UV/vis spectroscopy as well as MALDI-TOF mass spectrometry.
