2887-11-8Relevant academic research and scientific papers
Synthesis and kaleidoscopic reactivities of bis(tritolylgermyl) bis(dimethylphenylphosphine)platinum(II)
Usui, Yoko,Fukushima, Takashi,Nanjo, Masato,Mochida, Kunio,Akasaka, Kuniyoshi,Kudo, Takako,Komiya, Sanshiro
, p. 810 - 811 (2007/10/03)
A series of tritolylgermylplatinum complexes Pt(GeAr3) 2-(PMe2Ph)2 (Ar = o-tol, m-tol, and p-tol) were prepared and kaleidoscopic reactivities were observed by only changing the substituents at the germyl tolyl groups: (1) cis-trans isomerization at platinum, (2) C-H bond activation of ortho methyl group, and (3) reductive elimination at Pt giving Ge-Ge bond. Copyright
