2889-63-6Relevant academic research and scientific papers
TRIMETHYLSILYL POLYPHOSPHATE (PPSE). A USEFUL REAGENT FOR THE BECKMANN REARRANGEMENT
Imamoto, Tsuneo,Yokoyama, Hideki,Yokoyama, Masataka
, p. 1803 - 1804 (1981)
Various oximes were rearranged smoothly to the corresponding amides in trimethylsilyl polyphosphate (PPSE) which was conveniently prepared from phosphorus pentoxide and hexamethyldisiloxane.
TETRACARBONYL NICKEL INDUCED REACTION OF gem-DIBROMOCYCLOPROPANES WITH ALCOHOLS OR AMINES. VERSATILE SYNTHESIS OF CYCLOPROPANECARBOXYLIC ACID DERIVATIVES
Hirao, Toshikazu,Harano, Yoshiyuki,Yamana, Yoshihiro,Ohshiro, Yoshiki,Agawa, Toshio
, p. 1255 - 1258 (2007/10/02)
Treatment of gem-dibromocyclopropanes with alcohols or amines in the presence of tetracarbonyl nickel affords the corresponding cyclopropanecarboxylates or -carboxamides, respectively.
