289-77-0Relevant academic research and scientific papers
Hetero-?-Systems, 7. Silabenzene
Maier, Guenther,Mihm, Gerhard,Baumgaertner, Richard Otto Wilhelm,Reisenauer, Hans Peter
, p. 2337 - 2350 (2007/10/02)
Flash pyrolysis of silacyclohexadiene derivatives 5k, 5m, and 7b yields silabenzene (1), which can be isolated in an argon matrix at 10 K. 1 exhibits characteristic IR and UV spectra.By photoexcitation a mutual interconversion between silabenzene (1) and dewarsilabenzene (2) can be achieved.
Thermal Dehydrogenation of 1-Sila-2,5-cyclohexadiene to Silabenzene
Maier, Guenther,Mihm, Gerhard,Reisenauer, Hans Peter
, p. 801 - 803 (2007/10/02)
Flash pyrolysis of 1-sila-2,5-cyclohexadiene (1) yields silabenzene (2), which can be identified spectroscopically using matrix isolation in argon at 10 K.On the contrary the isomeric conjugated 1-sila-2,4-cyclohexadiene (3) forms under identical conditions only traces of silabenzene.
