2890-96-2

Basic information

• Product Name: (6S)-bicyclo[2.2.1]hept-2-ene-6-carbonitrile
• Synonyms: (6S)-bicyclo[2.2.1]hept-2-ene-6-carbonitrile;exo-Bicyclo[2.2.1]hept-5-ene-2-carbonitrile;Nsc76083
• CAS NO: 2890-96-2
• Molecular Formula: C₈H₉N
• Molecular Weight: 119.16
• Mol File: 2890-96-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 205.2 °C at 760 mmHg
• Flash Point: 65.6 °C
• Appearance: /
• Density: 1.06g/cm³
• Vapor Pressure: 0.254mmHg at 25°C
• Refractive Index: 1.531
• CAS DataBase Reference: (6S)-bicyclo[2.2.1]hept-2-ene-6-carbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (6S)-bicyclo[2.2.1]hept-2-ene-6-carbonitrile(2890-96-2)
• EPA Substance Registry System: (6S)-bicyclo[2.2.1]hept-2-ene-6-carbonitrile(2890-96-2)

Safety Data

• Hazardous Substances Data: 2890-96-2(Hazardous Substances Data)

Usage

General Description

(6S)-bicyclo[2.2.1]hept-2-ene-6-carbonitrile, also known as norcarane nitrile, is a bicyclic organic compound with a carbonitrile functional group. It is commonly used as an intermediate in organic synthesis, particularly in the production of pharmaceuticals and agrochemicals. This chemical is highly stable and can be stored for extended periods without degradation or loss of potency. Its unique structure and properties make it a valuable building block for the creation of various complex molecules. Additionally, (6S)-bicyclo[2.2.1]hept-2-ene-6-carbonitrile has potential applications in the development of new materials and in the field of organic electronics.

InChI:InChI=1/C8H9N/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-8H,3-4H2/t6?,7?,8-/m1/s1

Upstream product

• 542-92-7 cyclopenta-1,3-diene 
• 107-13-1 acrylonitrile 
• 71338-99-3 6exo-cyano-2exo-norbornyl p-toluenesulfonate 

Downstream Products

• 5257-46-5 (bicyclo<2.2.1>heptene-5 yle-2)-1 propanone-1, endo 
• 5257-46-5 1-bicyclo(2.2.1)-hept-5-en-2-yl propanone 
• 18776-20-0 (1S,2R,4S,5S)-3-Oxa-tricyclo[3.2.1.0^2,4]octane-6-carbonitrile 
• 1360557-43-2 2-(phenylsulfinyl)bicyclo[2.2.1]hept-5-ene-2-carbonitrile 
• 109240-01-9 (1RS,2SR,4RS)-2-(phenylsulfinyl)bicyclo[2.2.1]hept-5-ene-2-carbonitrile 
• 6945-87-5 2-chlorobicyclo<2.2.1>hept-5-ene-2-carbonitriles 
• 6945-87-5 (1R*,2S*,4R*)-2-chlorobicyclo[2.2.1]hept-5-ene-2-carbonitrile 
• 5453-80-5 exo-2-formylbicyclo[2.2.1]hept-5-ene 
• 51757-84-7 (+/-)-2-methyl-norborn-5-ene-2endo-carboxylic acid amide 
• 102939-71-9 [(1R,2R,4S,5S,6S)-6-(3-Methoxy-benzyl)-3-oxa-tricyclo[3.2.1.0^2,4]oct-6-yl]-propynoic acid methyl ester 
• 102939-73-1 [(1S,2R,4S)-2-(3-Methoxy-benzyl)-bicyclo[2.2.1]hept-5-en-2-yl]-propynoic acid methyl ester 
• 102939-75-3 (1S,4S,5R)-5-(2,2-Dibromo-vinyl)-5-(3-methoxy-benzyl)-bicyclo[2.2.1]hept-2-ene 
• 102939-69-5 (1S,2R,4S)-2-(3-Methoxy-benzyl)-bicyclo[2.2.1]hept-5-ene-2-carbaldehyde 
• 111099-08-2 endo (methyl-2 phenyl-3 trimethylsiloxy-3 propanone-1 yl)-5 bicyclo<2.2.1> heptene-2 

Relevant articles and documents

Enhanced Diels-Alder reactions: on the role of mineral catalysts and microwave irradiation in ionic liquids as recyclable media

This manuscript explores in detail the combined effect of solid supports or microwave irradiation in ionic liquids on a series of Diels-Alder reactions involving 1,3-cyclopentadiene and numerous dienophiles.

Rearrangements of 5- and 6-Cyano-2-norbornyl Cations

Hydroboration of the 5-norbornene-2-carbonitriles 11 afforded 5- and 6-hydroxynorbornane-2-carbonitriles (9a, 10a) along with the analogous ketones 12, 13. 5- and 6-aminonorbornane-2-carbonitriles (17a, 18a) were obtained either from the endo-brosylates 1