289035-33-2

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 138499-16-8 2-[(tert-butyldiphenylsilyl)oxy]ethanol 
• 115869-43-7 (tert-butyldiphenylsilanyloxy)acetaldehyde 
• 289035-32-1 1-(tert-butyl-diphenyl-silanyloxy)-3-methyl-6-trimethylsilanyl-hex-3-en-5-yn-2-ol 

Downstream Products

• 289035-35-4 C₄₀H₄₄O₅Si 
• 289035-34-3 (3Z,5Z)-1-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-nona-3,5-diene-2,7-diol 
• 289035-36-5 tert-Butyl-((2E,4E,6E)-3-methyl-nona-2,4,6-trienyloxy)-diphenyl-silane 

Relevant academic research and scientific papers

Stereoselective synthesis of all-trans methyl substituted polyenes by reductive elimination and application to the synthesis of all-trans 3-methyl- nona-2,4,6-trienol

The stereoselective synthesis of all-trans 3-methyl-nona-2,4,6-trienol 2 by reductive elimination of the corresponding 1,6-dibenzoate-2-methyl- 2(Z),4(Z)-diene is described. This result shows that reductive elimination can be extended to the formation of all-trans methyl substituted polyenes which are present in many natural products biosynthetically made from isoprenic units. (C) 2000 Elsevier Science Ltd.