28915-54-0

Upstream product

• 7727-37-9 nitrogen 

Downstream Products

• 36352-27-9 {WH4(dppe)2} 
• 850414-20-9 [W(⁽¹⁵⁾N₂)2(1,2-bis(diphenylphosphino)ethane)2] 
• 83632-66-0 ⁽²⁾H₄W((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2 
• 82307-44-6 azidobis[1,2-bis(diphenylphosphino)ethane]nitridotungsten 

Relevant academic research and scientific papers

Double deprotonation of coordinated ethylimide to CH3CN: Molecular mechanism and relevance to the chemistry of Mo and W organoimides

Reaction of [MCl(NEt)(dppe)2]Cl (M = Mo, W) with n-BuLi in tert-butyl methyl ether under an N2 atmosphere yields the M(0) bis(dinitrogen) complexes [M(N2)2(dppe)2] and acetonitrile. A mechanism is proposed for this reaction which involves an anionic chloro-acetonitrile intermediate. The implications of these findings to the chemistry of Mo and W organoimides are discussed. The Royal Society of Chemistry 2006.