289505-53-9

Upstream product

• 18107-18-1 diazomethyl-trimethyl-silane 
• 100-39-0 benzyl bromide 
• 213594-43-5 1,6:3,4-dianhydro-2-O-benzyl-β-D-altropyranose 
• 289505-45-9 1,6-Anhydro-3-azido-2-O-benzyl-3-deoxy-β-D-mannopyranose 
• 289505-51-7 ((2R,3R,4S,5S)-5-Benzyloxy-3-hydroxy-2-prop-2-ynyl-tetrahydro-pyran-4-yl)-methyl-carbamic acid tert-butyl ester 
• 289505-46-0 Acetic acid (2R,3S,4S,5S,6R)-5-acetoxy-6-acetoxymethyl-4-azido-3-benzyloxy-tetrahydro-pyran-2-yl ester 
• 289505-49-3 [5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-tetrahydro-pyran-4-yl]-methyl-carbamic acid tert-butyl ester 
• 289505-48-2 [5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-4-yl]-carbamic acid tert-butyl ester 
• 289505-43-7 (S)-4-[(2R,3R,4S,5S)-5-Benzyloxy-4-(tert-butoxycarbonyl-methyl-amino)-3-hydroxy-tetrahydro-pyran-2-ylmethyl]-2-tert-butoxycarbonylamino-pent-4-enoic acid methyl ester 
• 289505-52-8 (S)-3-{2-[(2R,3R,4S,5S)-5-Benzyloxy-4-(tert-butoxycarbonyl-methyl-amino)-3-hydroxy-tetrahydro-pyran-2-ylmethyl]-oxiranyl}-2-tert-butoxycarbonylamino-propionic acid methyl ester 
• 1053692-22-0 (S)-4-[(2R,3R,4R,5S)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methylamino-tetrahydro-pyran-2-ylmethyl]-2-tert-butoxycarbonylamino-pent-4-enoic acid methyl ester 

Relevant academic research and scientific papers

Total synthesis of (-)-dysiherbaine, a novel neuroexcitotoxic amino acid

A total synthesis of (-)-dysiherbaine, a neuroexcitotoxic amino acid isolated from the Micronesian marine sponge Dysidea herbacea, starting from a carbohydrate precursor, is described. The present synthesis features a palladium(0)-catalyzed cross-coupling of the 6/5-bicyclic core with an amino acid residue. (C) 2000 Elsevier Science Ltd.