2896-91-5

Basic information

• Product Name: [7S,(+)]-7-Ethyl-1,4,5,6,7,8,9,10-octahydro-2H-3,7-methanoazacycloundecino[5,4-b]indole-9β-carboxylic acid methyl ester
• Synonyms: Vincadine;(+)-Vincadine;[7S,(+)]-7-Ethyl-1,4,5,6,7,8,9,10-octahydro-2H-3,7-methanoazacycloundecino[5,4-b]indole-9β-carboxylic acid methyl ester
• CAS NO: 2896-91-5
• Molecular Formula: C21H28N2O2
• Molecular Weight: 340.45922
• Mol File: 2896-91-5.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [7S,(+)]-7-Ethyl-1,4,5,6,7,8,9,10-octahydro-2H-3,7-methanoazacycloundecino[5,4-b]indole-9β-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [7S,(+)]-7-Ethyl-1,4,5,6,7,8,9,10-octahydro-2H-3,7-methanoazacycloundecino[5,4-b]indole-9β-carboxylic acid methyl ester(2896-91-5)
• EPA Substance Registry System: [7S,(+)]-7-Ethyl-1,4,5,6,7,8,9,10-octahydro-2H-3,7-methanoazacycloundecino[5,4-b]indole-9β-carboxylic acid methyl ester(2896-91-5)

Safety Data

• Hazardous Substances Data: 2896-91-5(Hazardous Substances Data)

Usage

Occurrence

The leaves of Amsonia tabernaemontana yield this alkaloid.

Upstream product

• 18374-17-9 (±)-vincadifformine 

Relevant articles and documents

Synthesis of vinca alkaloids and related compounds part 94 [1]. Epimerization of compounds with aspidospermane and D-secoaspidospermane skeleton [section]

The individual epimerization steps of vincadifformine (1), deethylvincadifformine isomers (2,3), their synthetic intermediates (4-13) as well as that of simpler compounds with D-secoaspidospermane skeleton (1517) were studied a) in protic medium (boiling deuteroacetic acidic) and b) under reductive (with sodium borodeuteride in boiling acetic acid, or with sodium borohydride in boiling deuteroacetic acid) conditions.

Total synthesis of indole and dihydroindole alkaloids. VI. The total synthesis of some monomeric vinca alkaloids: dl vincadine, dl vincaminoreine, dl vincaminorine, dl vincadifformine, dl minovine and dl vincaminoridine

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