289660-60-2Relevant academic research and scientific papers
Reactivity of Cp Rh 16e half-sandwich complexes containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligand. Intermediates in the catalyzed trimerization of methyl acetylene carboxylate and phenylacetylene
Herberhold, Max,Yan, Hong,Milius, Wolfgang,Wrackmeyer, Bernd
, p. 4289 - 4294 (2008/10/08)
Reactions of the 16-electron (16e) half-sandwich complexes Cp*Rh[E2C2(B10H10)] [E = S (1S), Se (1Se)] with methyl acetylene carboxylate and phenylacetylene were studied in order to obtain information on both the primary addition products and the potential catalyzed oligomerization of the alkynes as a function of reaction conditions.
