289667-02-3Relevant articles and documents
Total synthesis of (+)-mycalamide A
Kagawa, Natsuko,Ihara, Masataka,Toyota, Masahiro
, p. 875 - 878 (2007/10/03)
A convergent total synthesis of (+)-mycalamide A is described. A Yb(OTf)3-TMSCl catalytic system is used to synthesize a trioxadecalin ring system, which contains the right segment of mycalamide A. In addition, a tetrahydropyran ring, which is
A stereoselective synthesis of the C-10 to C-18 (right-half) fragment of mycalamides employing lewis acid promoted intermolecular aldol reaction.
Toyota,Hirota,Hirano,Ihara
, p. 2031 - 2034 (2007/10/03)
[reaction: see text] Beginning with D-mannitol, a stereoselective synthesis of the right-half segment of the mycalamides has been accomplished by employing Lewis acid catalyzed intermolecular aldol reaction and oxypalladation as the key steps.