289901-44-6Relevant academic research and scientific papers
Synthesis and characterization of [OsCl2(=C=CHR)(PPh 3)2] and related complexes
Wen, Ting Bin,Hung, Wai Yiu,Zhou, Zhong Yuan,Lo, Man Fung,Williams, Ian D.,Jia, Guochen
, p. 2837 - 2846 (2007/10/03)
Treatment of [OsCl2(PPh3)3] with HC≡CR (R = Ph, p-tolyl, CMe3) in the presence of HCl gives the corresponding trichloro(carbyne) complexes [OsCl3(≡CCH 2R)(PPh3)2] in g
Unexpected formation of osmium carbyne and vinylidene complexes from the reaction of OsCl2(PPh3)3 with HC triple bond CCMe3
Wen, Ting Bin,Yang, Sheng-Yong,Zhou, Zhong Yuan,Lin, Zhenyang,Lau, Chak-Po,Jia, Guochen
, p. 3757 - 3761 (2008/10/08)
The reaction of osmium vinylidene complexes with HC triple bond CCMe3 was investigated. The formation of osmium carbyne and vinylidene complexes was observed. The complex was characterized by NMR spectroscopy and X-ray diffraction. The solid st
