290820-47-2

Basic information

• Product Name: 2-Propenal, 3-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyphenyl]-, (2E)-
• CAS NO: 290820-47-2
• Molecular Formula: C16H24O3Si
• Molecular Weight: 292.45
• Mol File: 290820-47-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2-Propenal, 3-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyphenyl]-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenal, 3-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyphenyl]-, (2E)-(290820-47-2)
• EPA Substance Registry System: 2-Propenal, 3-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyphenyl]-, (2E)-(290820-47-2)

Safety Data

• Hazardous Substances Data: 290820-47-2(Hazardous Substances Data)

Usage

General Description

2-Propenal, 3-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyphenyl]-, (2E)-, also known as (E)-3-(4-tert-butyldimethylsilyloxy-3-methoxyphenyl)acrylic aldehyde, is a chemical compound with the molecular formula C18H28O3Si. It is an aldehyde compound with a phenyl group and a dimethyl silyl ether functional group. This chemical is commonly used in organic synthesis and as a reagent in chemical reactions. It has potential uses in pharmaceutical and agrochemical industries, and it is important to handle it with proper safety precautions due to its potential hazardous properties.

Upstream product

• 290820-48-3 (E)-3-( 4-( (tert-butyldimethylsilyl)oxy)-3-methoxyphenyl)prop-2-en-1-ol 
• 214330-24-2 3-[3-methoxy-4-(tert-butyldimethylsiloxy)phenyl]-1-propene 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 4046-02-0 ethyl 4-hydroxy-3-methoxycinnamate 
• 121-33-5 vanillin 
• 1485529-16-5 (E)-ethyl 3-(4-((tert-butyldimethylsilyl)oxy)-3-methoxyphenyl)acrylate 
• 14371-10-9 (E)-3-phenylpropenal 
• 458-36-6 trans-coniferyl aldehyde 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 911682-17-2 4-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-but-3-en-2-ol 
• 1093121-05-1 (2E,4E)-5-[4-[[tert-butyldimethylsilyl]oxy]-3-methoxyphenyl]-penta-2,4-dienoate 
• 458-36-6 trans-coniferyl aldehyde 
• 1612146-72-1 (E)-4-(3-((2-amino-4,5,6,7-tetrahydrobenzo[d] thiazol-6-yl)(propyl)amino)prop-1-en-1-yl)-2-methoxyphenol 
• 290820-44-9 8'-phthalimidooctyl 5-deoxy-5-(E-4-O-(tert-butyldimethylsilyl)-3-methoxycinnamyl)-thio-α-L-arabinofuranoside 
• 290820-50-7 8'-phthalimidooctyl 5-deoxy-5-thio-(E-4-hydroxy-3-methoxycinnamyl)-α-L-arabinofuranoside 
• 290820-49-4 E-4-O-(tert-butyldimethylsilyl)-3-methoxycinnamyl thiolacetate 
• 290820-43-8 E-4-O-(tert-butyldimethylsilyl)-3-methoxycinnamyl thiol 
• 590365-95-0 phenethyl-thiocarbamic acid O-{3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-1-[2-(4-trifluoromethyl-phenyl)-ethyl]-propyl} ester 
• 634590-80-0 1-{3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-1-ethyl-propyl}-1,3-diphenethyl-thiourea 
• 634590-66-2 1-benzyl-1-{3-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-1-ethyl-propyl}-3-phenethyl-thiourea 
• 590365-96-1 phenethyl-thiocarbamic acid O-(1-{2-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-ethyl}-4-phenyl-butyl) ester 

Relevant articles and documents

Modular synthesis of (E)-cinnamaldehydes directly from allylarenes via a metal-free DDQ-mediated oxidative process

An efficient synthesis of (E)-cinnamaldehydes by a metal-free DDQ-mediated oxidative transformation of allylarenes was developed. The protocol provides a practical method to prepare diverse (E)-cinnamaldehydes with broad functional group tolerance in good to excellent yields, including easy access to natural products randainal and geranyloxy sinapyl aldehyde from plant extracts. Finally, the mechanism of a single-electron transfer process was proposed.

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