29105-03-1

Basic information

• Product Name: Methanesulfonic acid, trifluoro-, cadmium salt
• CAS NO: 29105-03-1
• Molecular Formula: CHF3O3S.1/2Cd
• Molecular Weight: 410.551
• Mol File: 29105-03-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, trifluoro-, cadmium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, trifluoro-, cadmium salt(29105-03-1)
• EPA Substance Registry System: Methanesulfonic acid, trifluoro-, cadmium salt(29105-03-1)

Safety Data

• Hazardous Substances Data: 29105-03-1(Hazardous Substances Data)

Upstream product

• 161363-91-3 xenontrifluoroacetate trifluoromethane sulfonate 

Downstream Products

• 201659-64-5 [Cd(C₃₅H₃₅NP₂S₂)(O₃SCF₃)2] 
• 19437-26-4 2,2'-dipyridyl ketone 

Relevant articles and documents

The direct synthesis of arylxenon trifluoromethanesulfonates via electrophilic substitution

The reaction of xenonbis(trifluoroacetate) and trifluoromethanesulfonic acid (triflic acid) gave the new, highly reactive unsymmetrical xenon-oxo species CF3COOXeOSO2CF3. Benzene derivates, containing electron withdrawing substituents such as -F, -CF3, -Cl or -NO2 were electrophilic attacked by this intermediate to yield arylxenon trifluoromethanesulfonates. Via this one-pot synthesis trifluoromethanesulfonates with the cations [Xe(2,4,6-F3C6H2)]+, [Xe(2-F-5-NO2C6H3)]+, [Xe(2-F-5-CF3C6H3)]+ and [Xe(3,5-(CF3)2C6H3)]+ were prepared. All compounds were characterized by their NMR, mass, and vibrational spectra. Additionally, several new arylxenon trifluoromethanesulfonates were detected by 129Xe-NMR spectroscopy as products of the reaction of 1,3-F2C6H4 and further deactivated benzenes with xenontrifluoroacetate trifluoromethane sulfonate. Fluoro substituents in ortho position to xenon significantly increase the thermal stability of the arylxenon trifluoromethanesulfonates obtained. The molecular structure of [Xe(2,6-F2C6H3)][OSO2CF3] was determined by single crystal diffraction methods. The arylxenon unit is weakly coordinated by one oxygen atom of the CF3SO3 anion. The salt crystallizes in the triclinic space group P1, a = 880.9(3) pm, b = 1093.9(5) pm, c = 1209.8(5) pm, α = 89.04(4)○, β = 74.23(3)○, γ = 86.03(3)○, Z = 4.