29114-73-6Relevant academic research and scientific papers
Selective and effective fluorination of organic compounds in water using selectfluor F-TEDA-BF4
Stavber, Gaj,Zupan, Marko,Jereb, Marjan,Stavber, Stojan
, p. 4973 - 4976 (2004)
(Chemical Equation Presented) Selective and effective fluorination of various types of organic compounds performed in water as the reaction medium using 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor F-TEDA-BF
Rh-Catalyzed arylation of fluorinated ketones with arylboronic acids
Dobson, Luca S.,Pattison, Graham
supporting information, p. 11116 - 11119 (2016/09/19)
The Rh-catalyzed arylation of fluorinated ketones with boronic acids is reported. This efficient process allows access to fluorinated alcohols in high yields under mild conditions. Competition experiments suggest that difluoromethyl ketones are more reactive than trifluoromethyl ketones in this process, despite their decreased electronic activation, an effect we postulate to be steric in origin.
