29120-59-0Relevant academic research and scientific papers
Polymer-supported tertiaryphosphine (JJ-TPP) as a green and recyclable organocatalyst for α-addition of carbon nucleophiles to α,β-unsaturated compounds
Liu, Hai-Ling,Jiang, Huan-Feng
, p. 2120 - 2125 (2008)
JJ-TPP has been demonstrated as an effective and reusable organocatalyst for α-addition of carbon nucleophiles to α,β-unsaturated compounds under very mild and environmentally friendly conditions. Under the optimized reaction conditions, the desired addition products were obtained as only E isomer with 18-90% isolated yields.
REVERSE MICROEMULSIONS MEDIATED SYTHESIS OF VINYLPHOSPHONIUM SALTS.
Larpent, C.,Meignan, G.,Patin, H.
, p. 2615 - 2618 (2007/10/02)
PPh3 reacts with activated alkynes in reverse (water-hydrocarbon) microemulsions giving specifically rise to a mixture of Z and E triphenylvinylphosphonium salts which are readily isolated in good yields.
