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[(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide is a chemical compound that features a nickel atom coordinated to a chiral ligand known as (S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl. This stable complex is characterized by its high efficiency and selectivity in catalyzing various chemical transformations, particularly in asymmetric hydrogenation reactions. The bromide ion acts as a counterion, balancing the charge of the complex. [(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide is highly valued for its ability to produce enantiomerically pure products, which is essential in the synthesis of pharmaceuticals, agrochemicals, and other fine chemicals.

291278-93-8

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291278-93-8 Usage

Uses

Used in Pharmaceutical Industry:
[(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide is used as a catalyst for asymmetric hydrogenation reactions in the production of pharmaceuticals. Its chiral nature allows for the creation of enantiomerically pure products, which is crucial for the development of effective and safe medications.
Used in Agrochemical Industry:
In the agrochemical industry, [(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide is utilized as a catalyst for the synthesis of various agrochemicals. Its ability to catalyze important chemical transformations with high efficiency and selectivity makes it a valuable tool in the development of new and improved products for agricultural applications.
Used in Fine Chemicals Industry:
[(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide is employed as a catalyst in the synthesis of fine chemicals, where its high efficiency and selectivity are essential for producing high-quality products with specific properties and applications.

Check Digit Verification of cas no

The CAS Registry Mumber 291278-93-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,9,1,2,7 and 8 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 291278-93:
(8*2)+(7*9)+(6*1)+(5*2)+(4*7)+(3*8)+(2*9)+(1*3)=168
168 % 10 = 8
So 291278-93-8 is a valid CAS Registry Number.

291278-93-8Upstream product

291278-93-8Downstream Products

291278-93-8Relevant articles and documents

Preparation, crystal structure analysis, and catalytic application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2

Spielvogel, Dirk J.,Davis, William M.,Buchwald, Stephen L.

, p. 3833 - 3836 (2002)

The preparation, crystal structure analysis, and catalytic application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2 were discussed. The relatively low binding affinity of Ni(0) with BINAP, which was utilized in the synthesis of BINAP itself, in a

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