291282-26-3Relevant articles and documents
Synthesis of caryophyllose. Use of n-BuLi/Na-O-t-Bu in the coupling of highly functionalized ketones and dithioacetals
Adinolfi, Matteo,Barone, Gaspare,Festa, Pasquale,Guariniello, Luigi,Iadonisi, Alfonso
, p. 4981 - 4985 (2000)
The C-4 branched monosaccharide caryophyllose 2a was synthesized by, convergent approach relying on the coupling of metalated dithioacetal 4b with ketone 3. Combined use of n-BuLi and t-Bu-ONa as deprotonation system for 4b turned out to be decisive for the success of this coupling. (C) 2000 Elsevier Science Ltd.