291286-38-9

Basic information

• Product Name: 2-(diphenylphosphanyl)-N-(2-hydroxyethyl)benzamide
• Synonyms: 2-(diphenylphosphanyl)-N-(2-hydroxyethyl)benzamide
• CAS NO: 291286-38-9
• Molecular Weight: 349.369
• Mol File: 291286-38-9.mol

Chemical Properties

• CAS DataBase Reference: 2-(diphenylphosphanyl)-N-(2-hydroxyethyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(diphenylphosphanyl)-N-(2-hydroxyethyl)benzamide(291286-38-9)
• EPA Substance Registry System: 2-(diphenylphosphanyl)-N-(2-hydroxyethyl)benzamide(291286-38-9)

Safety Data

• Hazardous Substances Data: 291286-38-9(Hazardous Substances Data)

Upstream product

• 141-43-5 ethanolamine 
• 291286-47-0 2,5-dioxopyrrolidin-1-yl 2-(diphenylphosphanyl)benzoate 
• 17261-28-8 ortho-diphenylphosphinobenzoic acid 

Downstream Products

• 291286-44-7 [Re(O)Cl3(κ2-2-(diphenylphosphanyl)-N-(2-hydroxyethyl)benzamide)] 

Relevant articles and documents

Neutral trichlorooxorhenium(V) complexes containing new heterofunctionalized phosphane ligands of the type PN2 and PNO

The new heterofunctionalized phosphane [(1R,2R)-N-(2-aminocyclohexyl)]- 2-(diphenylphosphanyl)benzamide (L1), N(2-aminoethyl)-2- (diphenylphosphanyl)benzamide (L2) and 2-(diphenylphosphanyl)-N-(2- hydroxyethyl)benzamide (L3) were synthesized by reaction of N-[2- (diphenylphosphanyl)benzoyloxy]succinimide (3) in dichloromethane with (1R,2R)(-)-diaminocyclohexane, ethylenediamine and ethanolamine, respectively. Reactions of [Re(O)Cl4]- with L1, L2 and L3, at a 1:1 metal/ligand molar ratio gave neutral trichlorooxorhenium(V) complexes of the type [Re(O)Cl3[κ2-L}] [L = L1 (4), L2 (5), L3 (6)]. The characterization of the compounds involved IR, 1H- and 31P-NMR spectroscopy, and X-ray crystallographic analysis for L1, 5 and 6. The Re atom: is six-coordinate in complexes 4-6, with an oxo ligand, three chloride ligands and a neutral bidentate heterofunctionalized phosphane ligand.