29149-73-3

Basic information

• Product Name: 4-Pentenoic acid, 2-acetyl-3-methyl-, ethyl ester
• CAS NO: 29149-73-3
• Molecular Formula: C10H16O3
• Molecular Weight: 184.235
• Mol File: 29149-73-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Pentenoic acid, 2-acetyl-3-methyl-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenoic acid, 2-acetyl-3-methyl-, ethyl ester(29149-73-3)
• EPA Substance Registry System: 4-Pentenoic acid, 2-acetyl-3-methyl-, ethyl ester(29149-73-3)

Safety Data

• Hazardous Substances Data: 29149-73-3(Hazardous Substances Data)

Upstream product

• 141-97-9 ethyl acetoacetate 
• 95151-35-2 3-buten-2-yl methyl carbonate 
• 103185-13-3 (E)-crotyl methyl carbonate 

Downstream Products

• 73392-94-6 2-Acetyl-3-methyl-2-<2-(phenylsulfinyl)-aethyl>-4-pentensaeure-aethylester 
• 73392-93-5 2-(1-Buten-3-yl)-3-oxo-6-phenylsulfinyl-hexancarbonsaeure-aethylester 

Relevant articles and documents

Ruthenium complex-catalyzed allylic alkylation of carbonucleophiles with allylic carbonates

Allylic carbonates except for allyl methyl carbonate reacted with carbonucleophiles such as ethyl acetoacetate in the presence of a catalytic amount of Ru(cod)(cot) in N-methylpiperidine at 80 deg C to give the corresponding monoallylated carbonucleophiles in high yields with high regioselectivity.The regioselectivity was quite different from that in the palladium-catalyzed reactions.The allylation of carbonucleophiles using allyl methyl carbonate selectively gave the diallylated carbonucleophiles in high yields.