2919-23-5Relevant articles and documents
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Meyer,K.,Rocek,J.
, p. 1209 - 1214 (1972)
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Thermal molecular beam matrix spectroscopy of cyclobutanol: temperature dependence of lineshapes and the conformation problem
Gunde, R.,Guenthard, Hs. H.
, p. 315 - 326 (1983)
Thermal molecular beam spectra of cyclobutanol isolated in Ar and Xe matrices and the temperature dependence of the ν(OH) Raman line are reported.Six matrix bands are shown by lineshape analysis to consist of 4-6 components which systematically decrease and increase with increasing temperature of the molecular beam source.Data on lineshape parameters and relative intensities are reported.Likewise the ν(OH) Raman band is shown to consist of four components which behave with respect to temperature dependence analogously to the matrix bands.The results will be discussed in terms of two models.
Ru-Photoredox-Catalyzed Decarboxylative Oxygenation of Aliphatic Carboxylic Acids through N-(acyloxy)phthalimide
Zheng, Chao,Wang, Yuting,Xu, Yangrui,Chen, Zhen,Chen, Guangying,Liang, Steven H.
supporting information, p. 4824 - 4827 (2018/08/24)
Decarboxylative aminoxylation of aliphatic carboxylic acid derivatives with (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) in the presence of ruthenium photoredox catalysis is reported. The key transformation entails a highly efficient photoredox catalytic cycle using Hantzsch ester as a reductant. The ensuing alkoxyamine can be readily converted to the corresponding alcohol in one pot, representing an alternative approach to access aliphatic alcohols under photoredox conditions.
Synthesis and kinetic regularities of the thermal decomposition of new hydrotrioxides of cyclic alcohols
Grabovskiy,Khalitova,Fedorova,Lobov,Rol’nik,Kabal’nova
, p. 464 - 468 (2017/03/08)
Cyclic hydrotrioxides were synthesized by low-temperature (?78 °C) ozonolysis of a series of cyclic alcohols and identified using 1H NMR spectra. The kinetic regularities of the thermal decomposition of the synthesized hydrotrioxides were studied. The experimental proof of the induced decomposition of alcohol hydrotrioxides was obtained for the first time using cyclohexanol hydrotrioxide as an example. The influence of cyclic substituents on the thermal stability of the hydrotrioxides is shown.