Cas 292-45-5,1,2,4,6-Tetrathiepane

292-45-5

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Basic information

Product Name: 1,2,4,6-Tetrathiepane
Synonyms: 1,2,4,6-Tetrathiepane
CAS NO:292-45-5
Molecular Formula: C₃H₆S₄
Molecular Weight: 0
EINECS: N/A
Product Categories: N/A
Mol File: 292-45-5.mol

Chemical Properties

Melting Point: N/A
Boiling Point: 307.4°C at 760 mmHg
Flash Point: 157.2°C
Appearance: /
Density: 1.395g/cm³
Vapor Pressure: 0.00131mmHg at 25°C
Refractive Index: 1.686
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: 1,2,4,6-Tetrathiepane(CAS DataBase Reference)
NIST Chemistry Reference: 1,2,4,6-Tetrathiepane(292-45-5)
EPA Substance Registry System: 1,2,4,6-Tetrathiepane(292-45-5)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 292-45-5(Hazardous Substances Data)

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Synthesis Reference(s)

Tetrahedron Letters, 22, p. 1939, 1981 DOI: 10.1016/S0040-4039(01)92873-4

Check Digit Verification of cas no

The CAS Registry Mumber 292-45-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 2,9 and 2 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 292-45:
(5*2)+(4*9)+(3*2)+(2*4)+(1*5)=65
65 % 10 = 5
So 292-45-5 is a valid CAS Registry Number.

InChI:InChI=1/C3H6S4/c1-4-2-6-7-3-5-1/h1-3H2

292-45-5Upstream product

292-45-5Downstream Products

292-45-5Relevant academic research and scientific papers

Multicomponent heterocyclization of carboxamides with H2S and CH2O

Akhmetova,Khairullina,Nadyrgulova,Kunakova,Dzhemilev

, p. 190 - 196 (2008/12/20)

Multicomponent heterocyclization of aliphatic amides with H2S and CH2O (1:3:2) in water-organic solvent mixture in the presence of BuONa led to the formation of 1,3,5-dithiazinane in high yield (30-95%) and with high selectivity (100%). Under these conditions benzamide gave 3,5-dibenzoyl-1,3,5-thiadiazinane in 74% yield, whereas due to ortho-effect the acetylsalicylamide with H2S and CH2O in a system BuOH-H2O without BuONa formed N-acetylsalicyloyl-1,3,5-dithiazinane (80%). Heterocyclization of α-aminosuccinic acid monoamide depending on the H2S and CH2O concentration occurred either at one or both NH2 yielding respectively mono-or bisdithiazinanes.

Cyclothiomethylation of aryl hydrazines with formaldehyde and hydrogen sulfide

Akhmetova,Nadyrgulova,Tyumkina,Starikova,Golovanov,Antipin,Kunakova,Dzhemilev

, p. 1824 - 1834 (2007/10/03)

Cyclothiomethylation of phenyl hydrazine with CH2O and H 2S in a ratio of 1: 3: 2 in an acidic medium (HCl) afforded previously unknown 3-phenyl-1,3,4-thiadiazolidine (35% yield) and N-phenyl(perhydro-1,3,5-dithiazin-5-yl)amine (35%

DARSTELLUNG UND EIGENSCHAFTEN VON SCHWEFELHALTIGEN SIEBENRINGEN 2. 1,2,4,6-TETRATHIEPAN

Weissflog, Eckhard

, p. 157 - 160 (2007/10/02)

Dilution of the yellow solution of polymeric thioform aldehyde in concentrated sulfuric acid with water leads to a mixture of compounds, which contains besides s-trithiane and an oxygen containing polymeric thioether some five to ten percent of 1,2,4,6-tetrathiepane.The properties of this compound are described.This reaction is an example for the conversion of polymer into cyclic thioethers.

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