29219-35-0Relevant academic research and scientific papers
Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control
Tenneti, Srinivasarao,Biswas, Souvagya,Cox, Glen Adam,Mans, Daniel J.,Lim, Hwan Jung,RajanBabu
supporting information, p. 9868 - 9881 (2018/07/25)
A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products, including di- and triterpenes and steroids. Installation of these ce
Synthesis and Highly Regioselective Diels-Alder Reaction of Functionalized Isoprenes Involving a Terminal Alkoxy Group and Chemical Modification of the Resulting Adducts.
Mandai, Tadakatsu,Osaka, Kazuhito,Kawagishi, Makoto,Kawada, Mikio,Otera, Junzo
, p. 3595 - 3600 (2007/10/02)
A variety of functionalized isoprenes involving a terminal alkoxy group (2 and 3) were newly synthesized according to eq 1, 2, and 3.These compounds proved to undergo a cycloaddition with various unsymmetric dienophiles highly regioselectively without a L
NOVEL SYNTHETIC METHOD FOR PIPERITENONES THROUGH DIELS-ALDER REACTION
Mandai, Tadakatsu,Osaka, Kazuhito,Kawagishi, Makoto,Kawada, Mikio,Otera, Junzo
, p. 797 - 804 (2007/10/02)
The Diels-Alder adduct obtained from 1-(2-phenylselenoethoxy)isoprene and methyl vinyl ketone was applied to synthesis of piperitenones.
Synthesis of Biflora-4,10(19),15-triene
Vig, O. P.,Sharma, M. L.,Kiran, Shashi,Singh, Jasvinder
, p. 746 - 748 (2007/10/02)
Alkylation of 2,6-dimethyl-8-(N-pyrrolidyl)-2,7-octadiene (II) with ethyl acrylate gives the ester aldehyde (III) which on Wittig olefination with isobutylenetriphenylphosphorane yields the triene ester (IV).LAH reduction of IV in the presence of a little
