29231-89-8Relevant academic research and scientific papers
Mild hydrosilylation of amides by platinum N-heterocyclic carbene catalysts
Pisiewicz, Sabine,Junge, Kathrin,Beller, Matthias
, p. 2345 - 2349 (2014)
The platinum-catalyzed hydrosilylation of amides to afford amines selectively is reported. By using defined platinum/N-heterocyclic carbene complexes, the reduction of secondary and tertiary amines takes place under mild conditions. The selective catalytic hydrosilylation of amides is reported. By using defined platinum/N-heterocyclic carbene (NHC) complexes, the reduction of secondary and tertiary amines proceeds in good yields under mild conditions. Copyright
Mild hydrosilylation of amides by platinum N-heterocyclic carbene catalysts
Pisiewicz, Sabine,Junge, Kathrin,Beller, Matthias
supporting information, p. 2345 - 2349 (2015/04/27)
The platinum-catalyzed hydrosilylation of amides to afford amines selectively is reported. By using defined platinum/N-heterocyclic carbene complexes, the reduction of secondary and tertiary amines takes place under mild conditions. The selective catalytic hydrosilylation of amides is reported. By using defined platinum/N-heterocyclic carbene (NHC) complexes, the reduction of secondary and tertiary amines proceeds in good yields under mild conditions.
Acyl Halide Induced Cleavage of N-Acylated Aminals
Boehme, Horst,Raude, Edgar
, p. 3421 - 3429 (2007/10/02)
Acyl halides attack N-acylated aminals 6 at the amine nitrogen as well as at the carboxamide group to form either N-halomethyl carboxamides 5 besides N,N-dialkyl carboxamides 11, or diacylamines 12 besides N,N-dialkylmethaneiminium halides 4.Depending on the variation of the substituents on both heteroatoms the cleavage may be directed to follow only one or the other pathway.Of highly synthetic interest is the broadly applicable preparation of methaneiminium salts 4 having bulky substituents on nitrogen by means of cleavage of the corresponding N,N-dialkyl-N'-formyl-N'-methylmethanediamines 6.
