292857-34-2

Basic information

• Product Name: (-)-(4S,5R,2'R)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one
• Synonyms: (-)-(4S,5R,2'R)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one
• CAS NO: 292857-34-2
• Molecular Weight: 365.557
• Mol File: 292857-34-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (-)-(4S,5R,2'R)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(4S,5R,2'R)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one(292857-34-2)
• EPA Substance Registry System: (-)-(4S,5R,2'R)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one(292857-34-2)

Safety Data

• Hazardous Substances Data: 292857-34-2(Hazardous Substances Data)

Upstream product

• 15185-01-0 N-tert-butyl-pyrrolidine 
• 112968-75-9 (5R)-(L-menthyloxy)-2(5H)-furanone 

Downstream Products

• 526-63-6 (-)-isoretronecanol 

Relevant articles and documents

Efficient radical addition of tertiary amines to electron-deficient alkenes using semiconductors as photochemical sensitisers

Tertiary amines can be added to electron-deficient alkenes with yields up to 98% in a radical chain reaction initiated by a photochemical electron transfer using inorganic semiconductors like TiO2 as sensitiser.

Highly efficient photochemical addition of tertiary amines to electron deficient alkenes. Diastereoselective addition to (5R)-5-menthyloxy-2[5H]- furanone

Tertiary amines derived from pyrrolidines can be added very efficiently (isolated yields up to 94%) to (5R)-5-mentyloxy-2[5H]-furanone. The addition, which follows a radical chain mechanism initiated by a photoinitiated electron transfer (PET) from the te