293321-16-1

Basic information

• Product Name: 3-(phenylselanyl)-1-(p-toluenesulfonyl)-2-piperidone
• Synonyms: 3-(phenylselanyl)-1-(p-toluenesulfonyl)-2-piperidone
• CAS NO: 293321-16-1
• Molecular Weight: 408.38
• Mol File: 293321-16-1.mol

Chemical Properties

• CAS DataBase Reference: 3-(phenylselanyl)-1-(p-toluenesulfonyl)-2-piperidone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(phenylselanyl)-1-(p-toluenesulfonyl)-2-piperidone(293321-16-1)
• EPA Substance Registry System: 3-(phenylselanyl)-1-(p-toluenesulfonyl)-2-piperidone(293321-16-1)

Safety Data

• Hazardous Substances Data: 293321-16-1(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 23438-61-1 1-(toluene-4-sulfonyl)piperidin-2-one 
• 675-20-7 piperidin-2-one 
• 98-59-9 p-toluenesulfonyl chloride 
• 23438-55-3 1-(4-Methylbenzene)sulfonyl-2H-hexahydroazepin-2-one 

Downstream Products

• 96013-55-7 1-[(4-methylphenyl)sulfonyl]-5,6-dihydro-1H-piperidin-2-one 

Relevant articles and documents

Nitrogen ylide-mediated cyclopropanation of lactams and lactones

Cyclopropanation of α,β-unsaturated δ-lactams and δ-lactones mediated by nitrogen ylides is described. The process tolerates different alkyl halides and gives efficiently bicyclo[4.1.0]heptanes in a totally stereoselective manner. On the other hand, ε-lac

Diels-Alder reactions of 5,6-dihydro-2(1H)-pyridones

The Diels-Alder reaction of achiral 5,6-dihydro-2(1H)-pyridones 12a,b and enantiopure 5,6-dihydro-2(1H)-pyridones 16a,b with a variety of diversely substituted buta-1,3-dienes under thermal or catalytic conditions, to give partially reduced isoquinolones 18-33 and 35-37, is reported. (C) 2000 Elsevier Science Ltd.

Diels-Alder reactions of 5,6-Dihydro-2(1H)-pyridones. Preparation of partially reduced cis-isoqninolones and cis-3,4-disubstituted piperidines

The Diels-Alder reactions of 5,6-dihydro-2(1H)-pyridones with a variety of diversely substituted butadienes to give partially reduced isoquinolones is reported. Reductive ozonolysis of the resulting octahydroisoquinolones gave cis-3,4-disubstituted piperidines.