29412-73-5

Upstream product

• 91226-68-5 3-bromo-1-diazobutan-2-one 
• 71-43-2 benzene 
• 1007-32-5 benzyl ethyl ketone 

Downstream Products

• 1206768-34-4 (R)-3-(4-chlorophenyl)-1-phenylbutan-2-one 
• 1206768-38-8 (R)-3-(4-methoxyphenyl)-1-phenylbutan-2-one 
• 1206768-37-7 (S)-ethyl 4-(3-oxo-4-phenylbutan-2-yl)benzoate 
• 1206768-36-6 (R)-ethyl 4-(3-oxo-4-phenylbutan-2-yl)benzoate 
• 59983-38-9 (S)-1,3-diphenylbutan-2-one 
• 67504-36-3 (R)-1,3-diphenylbutan-2-one 
• 5355-63-5 3-hydroxy-4-phenyl-2-butanone 
• 1221065-83-3 (R,E)-3-methyl-1,6-diphenylhex-4-en-2-one 
• 1221065-78-6 (S,E)-3-methyl-1,6-diphenylhex-4-en-2-one 
• 78156-65-7 1-acetyl-2-phenylacetoxynaphthalene 
• 103-82-2 phenylacetic acid 
• 78156-62-4 1-phenyl-2-ethylnaphtho<2,1-b>furan 
• 78156-61-3 1-methyl-2-benzylnaphtho<2,1-b>furan 

Relevant academic research and scientific papers

Cu-catalyzed synthesis of tetrasubstituted 2,3-allenols through decarboxylative silylation of alkyne-substituted cyclic carbonates

An efficient and mild Cu-catalyzed protocol has been developed for the decarboxylative silylation of alkyne-functionalized cyclic carbonate substrates affording 2,3-allenols featuring four different substituents. This practical methodology gives access to a wide scope of tetrasubstituted functionalized allenes in excellent yields.

Alkylation of Benzene with α-Diazoketones via Cycloheptatrienyl Intermediates

Benzyl ketones can be synthesised efficiently from benzene and α-diazoketones with sequential catalysis by rhodium(II) trifluoroacetate and trifluoroacetic acid; the process involves cycloheptatrienyl intermediates.