294183-84-9

Upstream product

• 21211-65-4 di(pyrrol-2-yl)methane 
• 17610-00-3 3,5-Di-tert-butylbenzaldehyde 
• 5970-45-6 zinc(II) acetate dihydrate 
• 187387-14-0 5,15-bis(3,5-di-tert-butylphenyl)porphyrin Zn^II 
• 557-34-6 zinc diacetate 
• 187387-14-0 [5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 

Downstream Products

• 278807-35-5 [(NCCHCHCC(C₆H₃(C(CH₃)3)2))2(NCCHCHCC(C))(NCCHCHCCH)Zn]2 
• 294183-85-0 [5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II) 
• 438457-40-0 [5,15-bis(3',5'-di-tert-butylphenyl)-10-(phenylethynyl)porphyrinato]zinc(II) 
• 438457-41-1 [5,15-bis(3',5'-di-tert-butylphenyl)-10-(4-nitrophenylethynyl)porphyrinato]zinc(II) 
• 1253940-75-8 10-(4-(tris(isopropyl)silylethynyl)phenyl)-5,15-di(3,5-ditertbutylphenyl)-zincporphyrin 
• 1010693-50-1 {5,15-bis[3,5-di(tert-butyl)phenyl]-10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato(2-)-κN²¹,κN²²,κN²³,κN²⁴}zinc(II) 
• 1010693-50-1 5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc 
• 1271735-32-0 [10,20-bis(3,5-di-tert-butylphenyl)-5-(3-benzothienyl)porphyrinato^(2-)-KN₂₁,KN₂₂,KN₂₃,KN₂₄]zinc(II) 
• 1271735-34-2 C₆₄H₅₆N₄S₂Zn 
• 1246450-05-4 10,20-bis(3,5-di-tert-butylphenyl)-5-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) 
• 1246450-10-1 10,20-bis(3,5-di-tert-butylphenyl)-5,15-bis-(1-pyrenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24 zinc(II) 
• 1271735-30-8 [10,20-bis(3,5-di-tert-butylphenyl)-5-(4,5-dimethoxyanthracen-1-yl)porphyrinato^(2-)-KN₂₁,KN₂₂,KN₂₃,KN₂₄]zinc(II) 
• 1138342-07-0 (5-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) 
• 923567-37-7 [Zn(N₄C₂₀H₈(C(O)C₆H₅)2(C₆H₃(C(CH₃)3)2)2)] 

Relevant academic research and scientific papers

Comparative Synthetic Strategies for the Generation of 5,10- and 5,15-Substituted Push-Pull Porphyrins

Contemporary applications in optics, medicine, solar cells, or material science are increasingly reliant on unsymmetrically substituted porphyrins. Due to their widespread applications and rise in demand we undertook a comparative analysis of synthetic strategies for meso-substituted porphyrins and present the synthesis of five different series of so-called A2BC push-pull porphyrins. The synthetic pathways used were applied to both 5,15-substituted and 5,10-substituted porphyrins, showcasing their flexibility and adaptability for different needs. Our approach combines well-known reactions with a strategic and logical stepwise functionalization allowing researchers to change and modify the electronic properties of these systems at various points of the syntheses. This facilitates the easy optimization of the synthesis of systems of current interest, for example, porphyrins for dye-sensitized solar cells (DSSCs) or for use in nonlinear optics, as well as fast generation of compound libraries.

Using the dye and pigment metalloporphyrin metalloporphyrin dye-sensitized solar cell and photoelectric conversion element

PROBLEM TO BE SOLVED: To provide a novel dye broad in the absorption wavelength range in the near infrared region and good in the phtoelectric conversion efficiency, and a photoelectric conversion device and a dye-sensitized solar cell using the same.SOLUTION: There are provided a porphyrin dye represented by formula (1), and a photoelectric conversion device and a dye-sensitized solar cell using the same. In the formula, Aand Aare an atom group having a 5- or 6-membered ring containing carbon atoms in the ring; Rand Rare a monovalent substituent; M is two hydrogen atoms, or atoms or an atom group covalently or coordinately bondable to phthalocyanine.

GREEN ZINC PORPHYRIN SENSITIZERS AND THEIR APPLICATIONS

The present invention relates to zinc porphyrin-based photosensitive dyes, specifically to zinc porphyrin-based photosensitive dyes with green transparency. The photosensitive dyes exhibit high push-pull ability in the zinc porphyrin-based structure, high

FUSING PORPHYRINS WITH POLYCYCLIC AROMATIC HYDROCARBONS AND HETEROCYCLES FOR OPTOELECTRIC APPLICATIONS

A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated heterocyclic rings can be obtained by a thermal fusion process. By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyciic rings or heterocyclic rings to the non-activated porphyrin core in meso,β fashion is achieved resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.

N-fused carbazole-zinc porphyrin-free-base porphyrin triad for efficient near-IR dye-sensitized solar cells

N-fused carbazole-zinc porphyrin-free-base porphyrin triad featuring an ethynyl-linkage was synthesized; efficient sensitization as long as 900 nm was demonstrated and an overall light-to-electricity conversion effciency of 5.21% was achieved under AM 1.5

VISIBLE/NIR PHOTODETECTORS

Porphyrin compounds are provided. The compounds may further comprise a fused polycyclic aromatic hydrocarbon or a fused heterocyclic aromatic. Fused polycyclic aromatic hydrocarbon s and fused heterocyclic aromatics may extend and broaden absorption, and modify the solubility, crystallinity, and film-forming properties of the porphyrin compounds. Additionally, devices comprising porphyrin compounds are also provided. The porphyrin compounds may be used in a donor/acceptor configuration with compounds, such as C60.

Perylene anhydride fused porphyrins as near-infrared sensitizers for dye-sensitized solar cells

Two perylene anhydride fused porphyrins 1 and 2 have been synthesized and employed successfully in dye-sensitized solar cells (DSCs). Both compounds showed broad incident monochromatic photon-to-current conversion efficiency spectra covering the entire vi

Meso-meso linked diporphyrin functionalized single-walled carbon nanotubes

Meso-meso linked diporphyrins ([H2Por]2) covalently functionalized soluble single-walled carbon nanotubes ([H2Por] 2-SWNTs) have been successfully prepared. As a light-harvesting chromophore, meso-meso linked di

Fused pyrene-diporphyrins: Shifting near-infrared absorption to 1.5 μm and beyond

(Figure Presented) Sticking together: Direct fusion of pyrene rings with diporphyrins can be achieved without prior activation of aromatic rings. This simple method gives pyrene-diporphyrin hybrids (see picture, C (pyrene) red, C (porphyrin) dark blue, N light blue, Zn green) with a high near-infrared (NIR) absorption that reaches the wavelengths required for use in telecommunications.

Post-modification of meso-meso-linked porphyrin arrays by iridium and rhodium catalyses for tuning of energy gap

meso-meso-Linked diporphyrins fabricated with multiple unsaturated carboxylic acid groups are efficiently synthesized by the use of transition-metal catalysis. Iridium-catalyzed direct borylation of meso-meso-linked diporphyrins furnish multi-borylated di