294190-53-7Relevant academic research and scientific papers
"Concerted" transition state, stepwise mechanism. Dynamics effects in C2-C6 enyne allene cyclizations
Bekele, Tefsit,Christian, Chad F.,Lipton, Mark A.,Singleton, Daniel A.
, p. 9216 - 9223 (2005)
The C2-C6 (Schmittel)/ene cyclization of enyne-allenes is studied by a combination of kinetic isotope effects, theoretical calculations, and dynamics trajectories. For the cyclization of allenol acetate 9, the isotope effect (kC
