294209-79-3

Upstream product

• 294209-78-2 (1R,2S,3S,4S)-2,3,4-tribenzyloxy-1-methoxy-5-methylenecyclooctane 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 3879-79-6 methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 343315-85-5 (1S,2R,3β,4S,5R)-2,3,4-tribenzyloxy-1,5-dimethoxycyclooctane 
• 294209-73-7 2,3,4-tri-O-benzyl-6,7-dideoxy-D-gluco-hept-6-eno-1,5-lactone 
• 127214-37-3 (2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-vinyl-tetrahydro-pyran 
• 294209-76-0 (1S,2R,3S,4S,5R)-2,3,4-tribenzyloxy-5-methoxycyclooctan-1-ol 
• 294209-77-1 (2S,3R,4R,5R)-2,3,4-tribenzyloxy-1,5-dimethoxycyclooctan-1-one 
• 294209-74-8 2,6-abhydro-3,4,5-tri-O-benzyl-1,7,8-trideoxy-D-gluco-octa-1,7-dienitol 

Relevant academic research and scientific papers

Synthesis of several members of a new family of carbasugars: The cyclooctane mimetics

The TIBAL-promoted Claisen rearrangement of carbohydrates, developed in our group, has been applied to vinyl glycosides derived from D-glucose to afford highly functionalized cyclooctene derivatives in a stereospecific manner. Subsequent manipulation of these compounds gave access to a new family of carbasugars: the glucose and idose cyclooctanic mimetics.