2944-09-4Relevant academic research and scientific papers
Contrasting two- and three-dimensional crystal properties of isomeric dialkyl phthalates
Plass, Katherine E.,Engle, Keary M.,Matzger, Adam J.
, p. 15211 - 15217 (2008/09/18)
Competitive adsorption occurs whenever a solution containing multiple components is in contact with a surface, and the relative adsorption strengths affect both the properties of the interface and the solution. To investigate this phenomenon, the factors
Alcoholysis of Aromatic Carboxylic Esters
Goedl, Sylvia,Trathnigg, Bernd,Junek, Hans
, p. 1185 - 1198 (2007/10/02)
The alcoholysis of various esters of aromatic carboxylic esters with octadecanol in the presence of lead stearate was investigated by chromatographic analysis of the reaction mixtures.The reactivity of the esters was found to be strongly affected by the substitution pattern of the aromatic nucleus as well as by the structure of the alkoxy group.Electron donating substituents in a suitable position lead to a remarkable increase in reactivity compared to the unsubstituted alkyl esters. - Keywords: Mono and polycarboxylic esters; Metal salt catalysis; Kinetics; Chromatographic analysis
