294675-18-6

Upstream product

• 563-52-0 2-chloro-3-butene 
• 2043-61-0 cyclohexanecarbaldehyde 
• 221676-47-7 1-cyclohexyl-2-methyl-but-3-en-1-ol 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 4784-77-4 (E/Z)-crotyl bromide 
• 598-32-3 2-hydroxy-3-butene 
• 504-61-0 (E)-but-2-enol 

Downstream Products

• 304459-85-6 4-methyl-1-phenyl-hex-5-en-3-ol 
• 169827-07-0 (E)-1-phenyl-hept-5-en-3-ol 

Relevant academic research and scientific papers

Rhodium-catalyzed carbonyl allylations by allylic alcohols with tin(II) chloride

Rhodium complexes such as [RhCl(cod)]2, [Rh(cod) 2]BF4, and [Rh(cod)(CH3CN)2]BF 4 function as catalysts for carbonyl allylations by allylic alcohols with 1 equimolar amount of tin(II) chlor

Iridium-catalyzed carbonyl allylations by allylic alcohols with Tin(II) chloride

Iridium complex [IrCl(cod)]2 can function as a catalyst for the allylation of aldehydes and ketones by allylic alcohols upon addition of an equimolar amount of SnCl2 in THF-H2O; the reaction is carried out between room temperature and 50 °C to give the corresponding homoallylic alcohols. Georg Thieme Verlag Stuttgart.

Development of a highly α-regioselective metal-mediated allylation reaction in aqueous media: New mechanistic proposal for the origin of α-homoallylic alcohols

This paper described a general method to obtain α-adduct homoallylic alcohols using indium, zinc, and tin in water. A new mechanism was proposed to account for the formation of these synthetically difficult-to-obtain molecules. Generally, this method can

The first In(OTf)3-catalyzed conversion of kinetically formed homoallylic alcohols into the thermodynamically preferred regioisomers: Application to the synthesis of 22α-sterols

A retro-ene reaction that generates the parent aldehyde and a sigmatropic rearrangement are involved in the In(OTf)3-catalyzed conversion of homoallylic alcohols 1 into the thermodynamically favored regioisomers 2. This method can be used for the stereocontrolled synthesis of linear homoallylic 22α-sterols from their readily accessible branched 22β isomers.

Regio- and diastereocontrol in carbonyl allylation by 1-halobut-2-enes with tin(II) halides

Regio- and diastereoselective carbonyl allylations of 1-halobut-2-enes with tin(II) halides are described. Tin(II) bromide in a dichloromethane- water biphasic system is an effective reagent for unusual α-regioselective carbonyl allylation of 1-bromobut-2

Stereochemical study of the allylation of aldehydes with allyl halides in cosolvent/water(salt)/Zn and in cosolvent/water(salt)/Zn/haloorganotin media

The stereochemical course of the allylation and propargylation of several aldehydes with crotyl and propargyl halides using zinc powder as the condensing agent in cosolvent/water(salt) media have been extensively studied. Radical ions of well-defined geom

α-Regioselective Carbonyl Allylation by an Allylic Tin Compound Prepared from 1-Bromobut-2-ene and Tin(II) Bromide at a Nonpolar Organic-Aqueous Interface

1-Bromobut-2-ene on a dichloromethane-water biphasic system at 25 deg C causes α-regioselective addition to aldehydes with SnBr2 to produce 1-substituted pent-3-en-1-ols, and causes γ-regioselective addition to aldehydes with SnBr2-Bu4NBr to produce 1-sub