294881-19-9

Upstream product

• 150712-74-6 9-iodo-10-phenylanthracene 
• 480996-05-2 {4'‐bromo‐[1,1'‐biphenyl]‐4‐yl}boronic acid 
• 334658-75-2 10-phenylanthracene-9-boronic acid 
• 92-86-4 4-(4-bromophenyl)bromobenzene 

Downstream Products

• 1072194-23-0 4-[4-(10-phenyl-9-anthryl)phenyl]-4'-(9-phenyl-9H-carbazol-3-yl)triphenylamine 

Relevant academic research and scientific papers

Evolution from Tunneling to Hopping Mediated Triplet Energy Transfer from Quantum Dots to Molecules

Efficient energy transfer is particularly important for multiexcitonic processes like singlet fission and photon upconversion. Observation of the transition from short-range tunneling to long-range hopping during triplet exciton transfer from CdSe nanocrystals to anthracene is reported here. This is firmly supported by steady-state photon upconversion measurements, a direct proxy for the efficiency of triplet energy transfer (TET), as well as transient absorption measurements. When phenylene bridges are initially inserted between a CdSe nanocrystal donor and anthracene acceptor, the rate of TET decreases exponentially, commensurate with a decrease in the photon upconversion quantum efficiency from 11.6% to 4.51% to 0.284%, as expected from a tunneling mechanism. However, as the rigid bridge is increased in length to 4 and 5 phenylene units, photon upconversion quantum efficiencies increase again to 0.468% and 0.413%, 1.5-1.6 fold higher than that with 3 phenylene units (using the convention where the maximum upconversion quantum efficiency is 100%). This suggests a transition from exciton tunneling to hopping, resulting in relatively efficient and distance-independent TET beyond the traditional 1 nm Dexter distance. Transient absorption spectroscopy is used to confirm triplet energy transfer from CdSe to transmitter, and the formation of a bridge triplet state as an intermediate for the hopping mechanism. This first observation of the tunneling-to-hopping transition for long-range triplet energy transfer between nanocrystal light absorbers and molecular acceptors suggests that these hybrid materials should further be explored in the context of artificial photosynthesis.

Anthracene Derivative, Material for Light-Emitting Element, Light-Emitting Element, Light-Emitting Device, and Electronic Appliance

An anthracene derivative represented by general formula (1) is provided. In the formula, Ar1, Ar3, Ar5, and Ar6 independently represent an aryl group having 6 to 13 carbon atoms, Ar2 and Ar4 independently represent an arylene group having 6 to 13 carbon atoms, and R1 to R8 independently represent hydrogen or an alkyl group having 1 to 4 carbon atoms. Ar1 to Ar6 may independently have a substituent. When Ar1 to Ar6 independently have two or more substituents, the substituents may be bonded to each other to form a ring. When a carbon atom of Ar1 to Ar6 has two substituents, the substituents may be bonded to each other to form a spiro ring.

Organic compound, anthracene derivative, and light-emitting element, light-emitting device, and electronic device in which the anthracene derivative is used

An anthracene derivative represented by a general formula (1) and an organic compound represented by a general formula (8) are provided. Further, by use of the anthracene derivative represented by the general formula (1), a light-emitting element with high emission efficiency can be obtained. Furthermore, by use of the anthracene derivative represented by the general formula (1), a light-emitting element that emits blue light with high color purity can be obtained.

ANTHRACENE DERIVATIVE

It is an object of the present invention to provide a novel material which has excellent light-emitting efficiency, a light-emitting element provided with the novel material, and a light-emitting device using the light-emitting element. The present invention provides an anthracene derivative represented by the following general formula (1).