295806-73-4Relevant articles and documents
Fluorescent material with piezochromism and slovatochromism and preparation method thereof
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Paragraph 0058-0061; 0079; 0080; 0100; 0101; 0121; 0122, (2021/05/12)
The invention relates to a fluorescent material with piezochromism and slovatochromism and a preparation method thereof, and belongs to the technical field of fluorescent materials. The fluorescent material with the piezochromism and the slovatochromism comprises a cyano-substituted p-phenylenevinylene compound, and the structural formula of the cyano-substituted p-phenylenevinylene compound is shown in the specification. The invention further discloses a preparation method of the fluorescent material with the piezochromism and the slovatochromism. The fluorescent material has slovatochromism and piezo-chromism performance at the same time, and compared with an existing fluorescent material, the application range is wider, and popularization is facilitated.
Role of synergistic π-π Stacking and X-H...Cl (X = C, N, O) H-bonding interactions in gelation and gel phase crystallization
Bhattacharjee, Subham,Bhattacharya, Santanu
supporting information, p. 7019 - 7022 (2015/04/22)
The self-assembly of p-pyridyl-ended oligo-p-phenylenevinylenes (OPVs) in ethanol leads to the formation of either hollow or solid microrods. The corresponding protonated OPVs with n-butyl chains induce transparent gelation and also gel phase crystallization owing to various synergistic noncovalent interactions. The chloride ion-selective gelation, AIEE and stimuli responsiveness of the gel are also observed. This journal is
Novel isoindigo-based conjugated polyelectrolytes: Synthesis and fluorescence quenching behavior with water-soluble poly(p-phenylenevinylene)s
Kou, Chun,He, Xiaolong,Jiang, Xueyu,Ni, Yifeng,Liu, Ling,Huangfu, Changxin,Liu, Kuan
, p. 2223 - 2237 (2015/10/05)
Two novel ID-based water-soluble conjugated polymers (+)-PIDPV and (-)-PIDPV were synthesized by Heck coupling reaction. These two polyelectrolytes are both consisted of isoindigo units and phenylenevinylene units. In the UV-vis absorption spectra, both (+)-PIDPV and (-)-PIDPV exhibit broad absorption bands that almost cover the whole visible region. Photophysical investigations reveal that the fluorescence of water-soluble PPV can be efficiently quenched by oppositely charged PIDPV at a very low concentration. Cationic PPV shows an efficient quenching effect with ΚSV = 1.01 × 106 M-1 in the presence of (-)-PIDPV while the anionic PPV gives a lager quenching constant with ΚSV = 1.71 × 106 M-1 in the presence of (+)-PIDPV. Furthermore, the blend films of water-soluble PPVs and oppositely charged PIDPV also exhibit excellent quenching effect. These properties suggest that (+)-PIDPV and (-)-PIDPV are promising materials in the application of ionic photoactive layer in the organic solar cells.