29584-99-4Relevant academic research and scientific papers
Fast oxidation of secondary alcohols by the bromate-bromide system using cyclic microwave heating in acidic water
P??kk?nen, Sanna,Pursiainen, Jouni,Lajunen, Marja
, p. 6695 - 6699 (2010)
We report an improved, gentle, cyclic microwave activation technique for the oxidation of secondary alcohols using nonhazardous hypobromous acid (BrOH) as the reagent in acidic water. Several aliphatic and aromatic secondary alcohols were successfully oxidized to the corresponding ketones using this technique in high yields and with only minor amounts of side products.
NOVEL INDOLIZINE DERIVATIVES, METHOD FOR PREPARING SAME, AND THERAPEUTIC COMPOSITIONS COMPRISING SAME
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Page/Page column 7, (2008/12/09)
The present invention is directed to compounds of formula (I): described as novel indolizine derivatives and to a method for their preparation along with pharmaceutical compositions thereof whose substituents are as described in the specification.
Experimental and theoretical studies on the reactivities of partially and fully fluorinated primary alkyl radicals
Bartberger, Michael D.,Dolbier Jr., William R.,Lusztyk,Ingold
, p. 9857 - 9880 (2007/10/03)
Absolute rate constants for hydrogen abstraction from n-Bu3SnH by a number of partially-fluorinated and fully fluorinated n-alkyl radicals have been measured. The C-H and C-C bond dissociation energies for a number of pertinent hydrofluorocarbons have been calculated by DFT. The rate data are compared with those for addition of the same radicals to styrene, and the reactivities of these radicals are discussed in terms of their electronegativies, their structure and the thermodynamics of their reactions.
SELECTIVE MONOBROMINATION OF KETONES BY BIS(DIMETHYLACETAMIDE)HYDROGEN TRIBROMIDE
Rodygin, M. Yu.,Mikhailov, V. A.,Savelova, V. A.
, p. 881 - 887 (2007/10/02)
A unified procedure for the α-monobromination of ketones by bis(dimethylacetamide)hydrogen tribromide in methanol is proposed.Methyl aryl ketones with donating and moderately accepting substituents in the ring readily enter into the reaction. 1-Bromo ketones are mostly formed during the bromination of methyl alkyl ketones.
