296252-69-2Relevant academic research and scientific papers
Modular chiral selenium-containing oxazolines: Synthesis and application in the palladium-catalyzed asymmetric allylic alkylation
Braga, Antonio L.,Lüdtke, Diogo S.,Sehnem, Jasquer A.,Alberto, Eduardo E.
, p. 11664 - 11671 (2005)
A new series of modular chiral selenium-containing oxazolines has been synthesized from inexpensive and commercially available l-serine and l-aspartic acid. These new compounds were evaluated as chiral ligands in the palladium-catalyzed asymmetric allylic
Expanded scope for the iridium-catalyzed asymmetric isomerization of primary allylic alcohols using readily accessible second-generation catalysts
Mantilli, Luca,Mazet, Clement
supporting information; scheme or table, p. 445 - 447 (2010/04/04)
A second generation of chiral (P,N)-iridium catalysts - readily accessible from inexpensive l-serine - displays expanded scope for the asymmetric isomerization of primary allylic alcohols.
Synthesis and application of chiral N-heterocyclic carbene-oxazoline ligands: Iridium-catalyzed enantioselective hydrogenation
Nanchen, Steve,Pfaltz, Andreas
, p. 4550 - 4558 (2008/02/07)
Two libraries of enantiomerically pure imidazolium salts bearing an oxazoline unit were synthesized. Deprotonation of the imidazolium salts and complexation of the resulting oxazoline-carbene ligands to iridium(i) was achieved in one step by mixing the im
Predetermined helical chirality in octahedral complexes with a novel pentadentate C2-symmetrical chiral bis(oxazoline) ligand
Seitz, Michael,Kaiser, Anja,Powell, Douglas R.,Borovik, Andrew S.,Reiser, Oliver
, p. 737 - 741 (2007/10/03)
The first example of the pentadentate bis(oxazolines) has been synthesized using a modular approach that readily provides access to this ligand class. This ligand allows the controlled transfer of carbon-centered to octahedral, metal-centered chirality, a
Optically active 4-Substituted (S)-2-Phenyl-2-oxazolines
Dehmlow, Eckehard Volker,Vor Der Brueggen, Jens
, p. 502 - 503 (2007/10/03)
(R)-4-Hydroxymethyl-2-phenyl-2-oxazoline (R)-1) was prepared from (L)-serine. The respective tosylate ((S)-2) was converted into sulfides (S)-4 and (S)-5, and sulfone (S)-6, useful starting materials for the elaboration of additional chiral centers. A pre
