29634-35-3Relevant academic research and scientific papers
Hydroxylation of carbanions with lithium teri-butyl peroxide acting as an oxenoid
Julia, Marc
, p. 15 - 24 (2007/10/03)
The lithium salt of terf-butyl hydroperoxide can convert alkyl, vinyl, aryl carbanions, acetylides and various enolates into the corresponding hydroxylated derivatives in good yields and under mild conditions. Eisevier.
Ortho-Metalated Aryl tert-Butyl Sulfones, Comparison with Other Directing Groups and New Methodology for Polysubstituted Aromatics
Iwao, M.,Iihama, T.,Mahalanabis, K. K.,Perrier, H.,Snieckus, V.
, p. 24 - 26 (2007/10/02)
The general utility of ortho-lithiated aryl tert-butyl sulfones for the synthesis of a variety of 2- and 2,6-carbon- and heteroatom-substituted products in good to excellent yields is described (Schemes I, VI, VII).
