296795-92-1

Upstream product

• 4464-18-0 1,3,5-tris(hydroxymethyl)benzene 
• 2672-58-4 1,3,5-tris-(methoxycarbonyl)benzene 
• 1189566-01-5 tetraethyl [5-(hydroxymethyl)-1,3-phenylene]bis(methylene)diphosphonate 
• 263164-95-0 Tetraethyl 5-methyl-1,3-phenylenebis(methylenephosphonate) 
• 19294-04-3 3,5-bis(bromomethyl)toluene 
• 200809-09-2 1,3-bis(bromomethyl)-5-hydroxymethylbenzene 

Downstream Products

• 205578-74-1 tetraethyl [5-(dimethoxymethyl)-1,3-phenylene]bis(methylenephosphonate) 
• 296795-93-2 (E,E)-3,5-Bis[2-(3,4,5-tripropoxyphenyl)ethenyl]benzaldehyde 
• 348621-34-1 3,5-bis{2'[3,5-bis[2'-(4-dibutylaminophenyl)vinyl]]}benzaldehyde 
• 348621-30-7 3,5-bis[2'-4(dibuthylaminophenyl)vinyl]benzaldehyde 
• 363622-80-4 3,5-Bis-[(E)-2-(4-trifluoromethyl-phenyl)-vinyl]-benzaldehyde 

Relevant academic research and scientific papers

Synthesis and supramolecular properties of a novel octaphosphonate porphyrin

Two complementary routes were developed for preparing novel octaphosphonate porphyrins. The use of protected/deprotected phosphonate-substituted precursors in the rational synthesis gave an overall yield 16%. A more streamlined synthetic path gave 21 % overall yield, of the target molecule. Octaphosphonate porphyrin possesses promising properties in supramolecular aggregate formation with cyclam. Cofacial reversible self-assembly of a meso-substituted octaphosphonate porphyrin with cyclam yields micrometer-long nanowires with a height of about 1-1.5 nm. The resulting wires were characterized by UV/Vis absorption, emission and atomic force microscopy and transmission electron microscopy. ( Wiley-VCH Verlag GmbH & Co. KGaA.

Synthesis, characterization, and optical response of dipolar and non-dipolar poly(phenylenevinylene) dendrimers

New dipolar and non-dipolar poly(phenylenevinylene) dendrimers bearing electron-donating and electron-withdrawing groups have been efficiently synthesized using Heck and Horner-Wadsworth-Emmons reactions. The photoluminescence of these systems may be tuned in the blue zone by choosing the appropriate peripheral groups. Despite the meta-substitution pattern, large Stokes shifts can be observed when π-donor and π-acceptor groups are connected by a m-phenylenevinylene system.

Stilbenoid dendrimers

The first five generations of the stilbenoid dendrimers 1(n) (n = 1-5) have been prepared by a combined coupled synthesis (between the generations of the dendrons 8-12) and convergent synthesis. Wittig-Horner reactions together with a protecting group tec

Stilbenoid dendrimers

A convergent synthesis in which all trans double bonds were constructed by Wittig-Horner reactions produces dendrimers of the general structure 1. With long-chain alkoxy residues on the periphery of the benzene rings, the first two generations display liq