2974-73-4Relevant articles and documents
Investigation of the reaction of α-thioamides, α-esters and α-nitriles with N-halosuccinimides
Kissane, Marie,Murphy, Maureen,Lynch, Denis,Ford, Alan,Maguire, Anita R.
, p. 7639 - 7649 (2008/12/20)
Investigation of the reaction of α-thioamides, α-esters and α-nitriles with NBS and NCS is described. The?scope of this stereoselective oxidative transformation to the β-haloacrylamides, β-acrylates and β-acrylonitriles has been determined. A mechanistic
Dienophilie des olefines captodatives: influence de l'encombrement sterique des α-alkylthioacrylonitriles sur la stereoselectivite des reactions de Diels-Alder
Boucher, Jean-Luc,Stella, Lucien
, p. 276 - 282 (2007/10/02)
The Diels-Alder reaction of cyclopentadiene with a series of α-alkyl-(or aryl)-thioacrylonitriles were investigated.The spontaneous cycloaddition occurs at room temperature affording adducts in excellent yield.The stereochemical assignments of the adducts