29771-48-0

Basic information

• Product Name: 3-allyl-3,5,7-trimethyl-4,6-cycloheptadiene-1,2-dione
• CAS NO: 29771-48-0
• Molecular Weight: 204.269
• Mol File: 29771-48-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-allyl-3,5,7-trimethyl-4,6-cycloheptadiene-1,2-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-allyl-3,5,7-trimethyl-4,6-cycloheptadiene-1,2-dione(29771-48-0)
• EPA Substance Registry System: 3-allyl-3,5,7-trimethyl-4,6-cycloheptadiene-1,2-dione(29771-48-0)

Safety Data

• Hazardous Substances Data: 29771-48-0(Hazardous Substances Data)

Upstream product

• 29771-47-9 2-allyloxy-3,5,7-trimethyltropolone 

Relevant articles and documents

A Dimethyl Sulfoxide-mediated Oxidation of Arylalkyl and Alkyl Alcohols to Corresponding Aldehydes and Ketones via Tropolonyl Ethers

The arylmethyl and diarylmethyl ethers of tropolones were oxidized to the corresponding carbonyl derivatives by heating in dimethyl sulfoxide.The free alcohols were oxidized at a much slower rate, suggesting that some sort of DMSO-linked intermediates are responsible for the oxidation.Inertness of free alcohols was proven by means of the cross-over experiments, including deuterium-labelling.This oxidation was applicable to alkyl ethers, but not to alkenyl ethers, which are known to cause the Claisen-rearrangement.