29776-92-9

Upstream product

• 1085-35-4 ammonium O,O'-diphenyl dithiophosphate 
• 2253-60-3 O,O-diphenyl phosphorodithioic acid 
• 373-02-4 nickel diacetate 
• 83864-14-6 nickel dichloride 

Downstream Products

• 58723-28-7 Ni(diphenylphosphorodithioate)2(o-phenylenediamine)2 
• 58723-28-7 [Ni(diphenylphosphorodithioate)(o-phenylenediamine)2](diphenylphosphorodithioate) 
• 58723-27-6 Ni(diphenylphosphorodithioate)2(2,2'-dipyridyl) 

Relevant academic research and scientific papers

Synthesis, spectroscopic characterization and structural studies of nickel complexes of O,O′-diaryl(dibenzyl) dithiophosphates: Crystal structures of Ni[S2P(OC6H4CH3-o) 2]2, Ni[S2P(OC6H4CH 3-m)2]2 and Ni[S2P(OCH 2Ph)2](2)

Purple-coloured, tetra-coordinated Ni(II) complexes, Ni[S 2P(OR)2]2 (R = o-, m-, p-OC6H 4Me, Ph and CH2Ph) have been obtained by reaction of NiCl2 with salts of corresponding O,O′-diaryl(dibenzyl) dithiophosphates and have been characterized by elemental analysis, UV, IR, 1H, and 31P NMR spectroscopy. Trends in the data are discussed. The crystal structures of Ni[S2P(OC6H 4Me-o)2]2, Ni[S2P(OC 6H4Me-m)2]2 and Ni[S 2P(OCH2Ph)2]2 are also described. Ni[S2P(OC6H4Me-o)2]2 crystallizes as monoclinic in the space group P21/n with cell parameters a = 9.069(2), b = 13.503(2), c = 23.735(4) ?, α = 90.00°, β = 90.11(1)°, γ = 90.00°, V = 2906.6(8) ?-3, Z = 4, R = 0.0351, Rw = 0.0787, Ni[S 2P(OC6H4CH3-m)2] 2 as triclinic in the space group P1? with cell parameters a = 9.4675(4), b = 12.8568(5), c = 13.1174(6) ?, α = 88.810(4)°, β = 83.416(5)°, γ = 73.711(4)°, V = 1522.4(1) ?-3,Z = 2, R = 0.0354, Rw = 0.0830, and Ni[S 2P(OCH2Ph)2]2 as triclinic in the space group P1? with cell parameters a = 10.887(2), b = 14.081(3), c = 16.238(3) ?, α = 72.70(3)°, β = 76.57(3)°, γ = 72.76(3)°, V = 2241.4(8) ?-3, Z = 2, R = 0.0365, R w = 0.0785. Each of these has a distorted square-planar geometry around nickel with MS4 coordination environment.

LIGAND EXCHANGE REACTIONS OF ANTIMONY(III) O,O-DISUBSTITUTED PHOSPHORODITHIOATES WITH NICKEL SALTS

Antimony(III) tris-(O,O-dialkyl phosphorodithioates) undergo ligand exchange reactions with nickel(II) chloride or nickel(II) octanoate in tetrahydrofuran solution to give nickel(II) bis-(O,O-dialkyl phosphorodithioates).The rates of the exchange reactions with nickel(II) chloride have been measured, and the rate constants can be correlated with polar substituent constants by use of the Taft-Hammett equation.The results suggest that the ligand exchange reactions occur by an initial SN2 type of attack of chloride ion on the antimony atom of the antimony(III) tris-(O,O-dialkyl phosphorodithioates).