29780-95-8

Upstream product

• 110-86-1 pyridine 
• 50-70-4 D-sorbitol 
• 76-83-5 trityl chloride 

Downstream Products

• 29780-96-9 1.6-Ditrityl-D-glucit-2.3.4.5-tetrastearinsaeureester 
• 1023310-53-3 2,3,4,5-tetra-O-benzyl-1,6-di-O-trityl-D-glucitol 
• 1607827-84-8 (2S,3S,4R,5R,6R)-2,3,4,5-tetrakis(benzyloxy)-6-hydroxycyclohexanone 
• 1607827-85-9 (2S,3S,4S,5S,6R)-6-acetoxy-2,3,4,5-tetrakis(benzyloxy)-cyclohexanone 
• 1607827-90-6 (2S,3S,4R,5S,6R)-2,3,4,5-tetrakis(benzyloxy)-6-hydroxycyclohexanone 
• 1607827-91-7 (2S,3S,4S,5R,6R)-6-acetoxy-2,3,4,5-tetrakis(benzyloxy)-cyclohexanone 
• 1607827-97-3 (1R,2S,3R,4R,5R,6R)-3,4,5,6-tetrakis(benzyloxy)cyclohexane-1,2-diol 
• 4261-26-1 O²,O³,O⁴,O⁵-tetramethyl-D-glucose 
• 256342-72-0 2,3,4,5-tetrakis-benzyloxyhexane-1,6-diol 
• 195873-70-2 (3R,4R,5R,6S)-3,4,5,6-tetra(benzoyloxy)-1,7-octadiene 
• 277744-76-0 2,3,4,5-tetra-O-benzyl-D-gluco-hexodialdose 
• 224433-58-3 (3R,4R,5R,6S)-3,4,5,6-tetra(benzyloxy)-cyclohexene 
• 161754-57-0 2,3,4,5-tetra-O-methyl-1,6-di-O-trityl-D-glucitol 

Relevant academic research and scientific papers

A straightforward synthesis of perbenzylated conduritols from alditols by ring closing olefin metathesis

The synthesis of perbenzylated conduritols A, E and F has been achieved in six steps by formal conversion of galactitol, D-mannitol and D-glucitol into the respective terminal dienes, followed by ring closing olefin metathesis. The Royal Society of Chemistry 1999.

Synthesis of allo - And epi -inositol via the NHC-catalyzed carbocyclization of carbohydrate-derived dialdehydes

A synthesis of carbocyclic sugars from carbohydrate-derived dialdehydes using organocatalysis has been developed. Sorbitol, mannitol, and galactitol were converted via 1,6-tritylation, perbenzylation or permethylation, detritylation, and Swern oxidation into 2,3,4,5-tetra-O-alkyl-dialdoses that were cyclized via the benzoin reaction promoted by a triazolium carbene. Manno- and galacto-configured dialdehydes gave predominantly single inosose stereoisomers in up to 75% yield if the mixture was acetylated prior to isolation while the gluco-dialdehyde afforded a mixture of three stereoisomers in 61% overall yield. The inososes were stereospecifically reduced using sodium borohydride and then deprotected to give allo- and epi-inositol in good yield that confirmed the structural and stereochemical assignments.

Improved stereochemical analysis of conformationally flexible diamines by binding to a bisporphyrin molecular clip

The relative stereochemistry of acyclic diamines with several stereogenic centers has been analyzed by NMR spectroscopy in combination with conformational deconvolution. Binding to a bisporphyrin molecular clip improves the stereochemical assignment signi

Separate synthesis and evaluation of glucitol bis-phosphate and mannitol bis-phosphate, as competitive inhibitors of fructose bis-phosphate aldolases

We report the first unambiguous syntheses of glucitol-1,6-bis-phosphate and mannitol-1,6-bis-phosphate and their competitive inhibition of various fructose bis-phosphate aldolases.

Asymmetric synthesis using reactions with modest group selectivity

The isomeric purity of products from certain group-selective reactions can be significantly amplified when reactions can occur sequentially.The theoretical basis for a strategy that exploits reactions with modest enantiotopic group selectivity for asymmet