29800-55-3

Basic information

• Product Name: bicyclo[6.1.0]nonan-2-one
• Synonyms: Bicyclo[6.1.0]nonan-2-one
• CAS NO: 29800-55-3
• Molecular Formula: C₉H₁₄O
• Molecular Weight: 138.2069
• Mol File: 29800-55-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 219.8°C at 760 mmHg
• Flash Point: 79.6°C
• Density: 1.007g/cm³
• Vapor Pressure: 0.117mmHg at 25°C
• Refractive Index: 1.49
• CAS DataBase Reference: bicyclo[6.1.0]nonan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: bicyclo[6.1.0]nonan-2-one(29800-55-3)
• EPA Substance Registry System: bicyclo[6.1.0]nonan-2-one(29800-55-3)

Safety Data

• Hazardous Substances Data: 29800-55-3(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 62249-35-8 (Z)-2-cycloocten-1-ol 
• 19935-88-7 N,N'-Dinitroso-N,N'-diaethoxycarbonyl-1,3-propandiamin 
• 108-94-1 cyclohexanone 
• 286-60-2 bicyclo[6.1.0]nonane 
• 1728-25-2 2-cycloocten-1-one 
• 3212-75-7 2-cycloocten-1-ol 
• 122950-18-9 (1R^*,8S^*)-bicyclo<6.1.0.>nonan-2-one 1,4-di-O-benzyl-L-threitol ketal 
• 29783-12-8 anti-(1α,2α,8α)-Bicyclo<6.1.0>nonan-2-ol 

Downstream Products

• 122950-18-9 C₂₇H₃₄O₄ 

Relevant articles and documents

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Another Role of Copper in the SimmonsSmith Reaction: Copper-catalyzed Nucleophilic Michael-type Cyclopropanation of a,β-Unsaturated Ketones

Cyclopropanation was performed using the Furukawa procedure with CH2I2/Et2Zn and a,β-unsaturated ketones. The reaction was performed in the presence of a copper salt. The reactivity was highly dependent on the substrate structure, and cyclopropanated products were obtained in better yields than those achieved using the original SimmonsSmith conditions with a ZnCu couple in some cases. Stereospecificity was observed in a certain case; however, the synthesis of an asymmetric version with a chiral ligand was not successful.