29865-53-0Relevant academic research and scientific papers
Enantioselective hydrogenation of α,β-disubstituted nitroalkenes
Li, Shengkun,Huang, Kexuan,Zhang, Xumu
, p. 8878 - 8881 (2014/08/05)
The first highly chemo- and enantioselective hydrogenation of α,β-disubstituted nitroalkenes was accomplished with rhodium/JosiPhos-J2 as a catalyst, with the yield and enantioselectivity of up to 95% and 94%, respectively. The α-chiral nitroalkanes will provide an entry to valuable chiral amphetamines which are otherwise not so easily accessed. This journal is the Partner Organisations 2014.
Asymmetric reduction of nitroalkenes with baker's yeast
Kawai, Yasushi,Inaba, Yoshikazu,Tokitoh, Norihiro
, p. 309 - 318 (2007/10/03)
Various α,β-disubstituted and trisubstituted nitroalkenes were chemoselectively reduced with baker's yeast to the corresponding nitroalkanes. Stereoselectivities of the reduction of α,β-disubstituted nitroalkenes were modest to low, and e.e.s up to 52% were obtained. Trisubstituted nitroalkenes could be reduced to the corresponding nitroalkanes with excellent enantioselectivities, moderate diastereoselectivities and in good yield.
REDUCTION OF AROMATIC NITROALKENES WITH BAKER'S YEAST
Takeshita, Mitsuhiro,Yoshida, Sachiko,Kohno, Yoichiro
, p. 553 - 562 (2007/10/02)
Aromatic nitroalkenes were reduced chemoselectively with baker's yeast to give the corresponding nitroalkanes.
Selective Reduction of Carbon-Carbon Double Bonds with an NAD(P)H Model-Acetic Acid System
Inoue, Yoshio,Imaizumi, Shin,Itoh, Hiromitsu,Shinya, Takao,Hashimoto, Harukichi,Miyano, Sotaro
, p. 3020 - 3022 (2007/10/02)
The carbon-carbon double bond in conjugated nitro and certain carbonyl compounds was reduced smoothly and selectively by Hantzsch ester (HEH), an NAD(P)H model, in the presence of a small amount of acetic acid.
