29915-94-4Relevant academic research and scientific papers
Sequential Radical Cyclization/Intermolecular Carbonyl Addition Reactions Initiated by Samarium(II) Iodide
Molander, Gary A.,Kenny, Caryn
, p. 1439 - 1445 (2007/10/02)
A sequential reductive coupling process promoted by samarium(II) iodide (SmI2) is described.Thus, ethyl 2-acetyl-2-methyl-5-hexenoate, upon treatment with SmI2 in the presence of a variety of aldehydes or ketones, undergoes an initial radical (ketyl) olef
