29943-56-4

Upstream product

• 16009-56-6 acetonitrile(trichloro)bis(triphenylphosphine)-rhenium(III) 
• 22031-12-5 [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] 

Downstream Products

• 141707-25-7 ReH₃(1,1,1-tris((diphenylphosphino)methyl)ethane)(AsPh₃) 
• 141726-07-0 ReH₃(1,1,1-tris((diphenylphosphino)methyl)ethane)(SbPh₃) 
• 141707-19-9 (η3-triphos)rhenium(V) pentahydride 

Relevant academic research and scientific papers

Synthesis and characterization of rhenium polyhydrides stabilized by the tripodal ligand MeC(CH2PPh2)3

The reaction of CH3C(CH2PPh2)3 (triphos) with in THF at reflux temperature yields 2-triphos)Re(O)Cl3> (3).Compound 3 is transformed into 2-triphos)ReH7> (4) by treatment with LiAlH4 in refluxing THF.The reaction of with triphos in refluxing toluene gives fac-3-triphos)ReCl3> (5) in excellent yield.Complex 5 is converted to the classical pentahydride 3-triphos)ReH5> (6) by treatment with NaBH4 at room temperature.The reductve elimination of H2 from 6 is promoted by monodentate ligands such as PPh3 and CO, giving substitution products of the formula 3-triphos)ReH3(L)> (L = PPh3 (7) or CO (8)).All the rhenium polyhydrides obtained have been characterized by spectroscopic techniques including IR and multinuclear variable-temperature NMR analysis.A detailed study of the spin-lattice relaxation time (T1) at variable temperature has shown that T1 cannot be used unambiguously to discriminate between classical and non-classical structures of rhenium polyhydrides.