30011-77-9Relevant academic research and scientific papers
Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: Optimization and mechanism study
Zhao, Na,Qiu, Li,Wang, Xiao,Li, Jianzhong,Jiang, Yi,Wan, Xiaobo
, p. 9665 - 9671,7 (2012)
Dibenzo[b,f][1,5]diazocines, a class of potential building blocks for novel electrochemical actuators, were synthesized via a novel, efficient acid-catalyzed reaction of 2-acylbenzoisocyanate at room temperature. Real-time NMR analysis and the captured intermediate showed the mechanism was an unprecedented cyclization of the isocyanate with the neighboring acyl group, followed by the dimerization.
A New Synthesis of Naphthopyrroles. Conversion of Naphthothiophene-4,9-diones to Naphthopyrrole-4,9-diones.
Marecki, Paul E.,Butke, Gregory P.
, p. 1497 - 1500 (2007/10/02)
A series of 2-substituted-4,9-dihydronaphthopyrrole-4,9-diones was prepared by the reaction of 4,9-dihydronaphthothiophene-4,9-diones with primary amines under mild conditions.The presence of halogen in the naphthothiophene-4,9-dione and the presence of hydroxyl, ether, or tertiary amine functions in the amine reagent do not interfere with the course of the reaction.
