30038-70-1Relevant academic research and scientific papers
INTERACTION OF PENTAFLUOROPHENOL WITH LEAD TETRAACETATE IN ACIDS
Kovtonyuk, V.N.,Kobrina, L.S.,Yakobson, G.G.
, p. 89 - 98 (1985)
The ability of polyfluorinated hydroxyaromatic compounds to be oxidised by radical and ionic mechanisms is discussed.Oxidation of pentafluorophenol by lead tetraacetate in hydrogen fluoride and trifluoroacetic acid gave the products of a reaction proceeding by an ionic mechanism - hexafluorocyclohexa-2,5-dienone and trifluoroacetoxydienones respectively.
AROMATIC FLUORINE DERIVATIVES. C. REACTIONS OF PENTAFLUOROPHENOL WITH VANADIUM, NIOBIUM, AND ANTIMONY FLUORIDES AND XENON DIFLUORIDE
Avramenko, A. A.,Bardin, V. V.,Karelin, A. I.,Krasil'nikov, V. A.,Tushin, P. P.,et. all
, p. 746 - 749 (2007/10/02)
Pentafluorophenol reacts with vanadium fluorides and xenon difluoride giving perfluoro-2,5-cyclohexadien-1-one and the products from dimerization of the pentafluorophenoxyl radical, i.e., perfluoro-6-phenoxy-2,4-cyclohexadien-1-one, perfluoro-4-phenoxy-2,5-cyclohexadien-1-one, and perfluoro-2-phenoxy-2,5-cyclohexadien-1-one.Antimony and niobium pentafluorides give stable complexes or the corresponding pentafluorophenolates with pentafluorophenol.
