300547-64-2

Upstream product

• 124738-96-1 2,3,4-tris-O-(phenylmethyl)-D-xylo-pentos-5-ulose 1-(O-methyloxime) 
• 124738-95-0 2,3,4-tri-O-benzyl-D-xylose-O-methyloxime 
• 18039-26-4 2,3,4-tri-O-benzyl-D-xylopyranose 

Relevant academic research and scientific papers

Radical cyclization in heterocycle synthesis. Part 9: A novel synthesis of aminocyclitols and related compounds via stannyl radical cyclization of oxime ethers derived from sugars

Stannyl radical addition-cyclization of oxime ethers derived from D-glucose, D-galactose, and D-xylose proceeded smoothly to afford alkoxyamino alcohols which were effectively converted into two types of glycosidase inhibitors or its candidates such as aminocyclitols, 1-deoxynojirimycin, and 1-deoxygalactostatin via reductive ring-expansion of trans alkoxyamino alcohols. (C) 2000 Elsevier Science Ltd.