300547-65-3

Upstream product

• 6386-24-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 
• 300547-61-9 (2S,3R,4S,5R)-2,3,4,6-Tetrakis-benzyloxy-5-hydroxy-hexanal O-methyl-oxime 
• 53008-63-2 methyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranoside 
• 100-44-7 benzyl chloride 
• 300547-62-0 2,3,4,6-tetrakis-O-(phenylmethyl)-D-lyxo-hexos-5-ulose 1-(O-methyloxime) 

Downstream Products

• 300547-68-6 [1R-(1α,2α,3β,4α,5α)]-2-amino-3,4,5-tris(phenylmethoxy)-1-[(phenylmethoxy)methyl]cyclopentanol 

Relevant academic research and scientific papers

Radical cyclization in heterocycle synthesis. Part 9: A novel synthesis of aminocyclitols and related compounds via stannyl radical cyclization of oxime ethers derived from sugars

Stannyl radical addition-cyclization of oxime ethers derived from D-glucose, D-galactose, and D-xylose proceeded smoothly to afford alkoxyamino alcohols which were effectively converted into two types of glycosidase inhibitors or its candidates such as aminocyclitols, 1-deoxynojirimycin, and 1-deoxygalactostatin via reductive ring-expansion of trans alkoxyamino alcohols. (C) 2000 Elsevier Science Ltd.